Marcus H. Sak

msak@g.harvard.edu

Education

Harvard University

Aug 2021–May 2026

Ph.D., Department of Chemistry and Chemical Biology

Advisor: Eric N. Jacobsen • Thesis: Enzymatic Principles in Selective Small-Molecule Catalysis

Yale University

2017–2021

B.S./M.S. in Chemistry

Summa cum laude, Phi Beta Kappa • GPA: 3.98/4.00

Research Experience

Merck & Co., Inc.

Feb–June 2025

Visiting Scientist, Process R&D Enabling Technologies

High-throughput and automated experimentation for combinatorial screening

Yale University

Jan 2018–May 2021

Advisor: Scott J. Miller

Peptide-catalyzed enantioselective reactions and associated mechanistic/computational studies

Justus-Liebig-Universität Giessen

May–Jul 2019

Advisor: Peter R. Schreiner

Synthesis, computational studies, and matrix isolation of minimal mercaptocarbenes

National University of Singapore

Jun 2015–Jul 2016

Advisor: Yixin Lu

Asymmetric phosphine catalysis of [3 + 2] and [3 + 3] cycloadditions

Publications

  1. Sak, M. H.†; Jiang, Y.†; Jacobsen, E. N.; Liu, R. Y. Dual-Ligand System for Mild Decarbonylative Suzuki–Miyaura Cross-Coupling of Aroyl Chlorides. ACS Catal. 2026, DOI: 10.1021/acscatal.5c08167.
  2. Sak, M. H.; Liu, R. Y.; Kwan, E. E.; Jacobsen, E. N. Accelerating the Discovery of Cooperative Catalysis. Nature 2025, 648, 333.
  3. Sak, M. H.; Jacobsen, E. N. Selective Noncovalent Catalysis with Small Molecules. Chem. Rev. 2025, 125, 8319.
  4. Sak, M. H.†; Lovinger, G. J.†; Jacobsen, E. N. Catalysis of An SN2 Pathway by Geometric Preorganization. Nature 2024, 632, 1052.
  5. Turek, A. K.; Sak, M. H.; Miller, S. J. Kinetic Analysis of a Cysteine-Derived Thiyl-Catalyzed Asymmetric Vinylcyclopropane Cycloaddition Reflects Numerous Attractive Noncovalent Interactions. J. Am. Chem. Soc. 2021, 143, 16173.
  6. Chan, Y.-C.; Sak, M. H.; Frank, S. A.; Miller, S. J. Tunable and Cooperative Catalysis for Enantioselective Pictet-Spengler Reaction with Varied Nitrogen-Containing Heterocyclic Carboxaldehydes. Angew. Chem. Int. Ed. 2021, 60, 24573.
  7. Coombs, G.; Sak, M. H.; Miller, S. J. Peptide‐Catalyzed Fragment Couplings that Form Axially Chiral Non‐C2‐Symmetric Biaryls. Angew. Chem. Int. Ed. 2020, 59, 2875.

Presentations

Talk: Enzymatic Principles in Selective Small-Molecule Catalysis. University of Copenhagen Special Seminar, June 2026 (upcoming), Denmark
Talk: Accelerating the Discovery of Cooperative Catalysis. Merck & Co. Invited Lecture, December 2025, Rahway, NJ
Talk: Catalytic Principles in Phosphonium Dealkylation towards P-Stereogenic Compounds. ACS DOC Graduate Research Symposium, July 2025, San Diego, CA
Talk: Catalytic Principles in Phosphonium Dealkylation towards P-Stereogenic Compounds. Johnson & Johnson Graduate Research Symposium, June 2025, San Diego, CA
Talk: Accelerating the Discovery of Cooperative Catalysis. Rowan Scientific Lecture Series, January 2025, Boston, MA
Poster: Catalysis of An SN2 Pathway by Geometric Preorganization. Stereochemistry Gordon Research Conference, July 2024, Newport, RI
Talk: Catalytic Enantioselective Arbuzov Reaction by Ion Pair Reorganization. Harvard Chemistry & Chemical Biology Symposium, May 2023, Cambridge, MA
Talk: Efficient data retrieval for large-scale smart city applications through applied Bayesian inference. IEEE International Conference on Intelligent Sensors, Sensor Networks, and Information Processing, 2015, Singapore (Best Paper Nomination)

Teaching

Harvard University

2022–2023

Teaching Fellow

• CHEM 105 (Advanced Organic Chemistry)

• CHEM 17 (Principles of Organic Chemistry), CHEM 20 (Organic Chemistry I)

Yale University

2018–2021

Quantitative Reasoning/Science Peer Tutor

• General Chemistry I/II

• Organic Chemistry I

• Physical Chemistry I/II

Fellowships

Industry-Sponsored Research Fellowship

2024–2026

Merck & Co., Inc.

DAAD Research Internship in Science and Engineering (RISE)

2019

German Academic Exchange Service

Alan S. Tetelman 1958 Fellowship for International Research in the Sciences

2019

Yale University

Honors & Awards

Certificate of Distinction in Teaching

2023

Harvard University

Exceptional Distinction in the Major

2021

Yale University • First award since 2015

Werner Bergmann Prize for Outstanding Senior in Chemistry

2021

Yale University

Mentoring

Harvard University

• L Thompson (Graduate student, 2025–present)

• Yichen Jiang (Visiting undergraduate, Peking University, Jun–Oct 2025)

• Maximilian Frank (Visiting Masters student, LMU Munich, May–Aug 2025)

• John Rezk (Graduate student, 2022–2025)

• Frank Lee (Harvard College undergraduate, 2022–2025)

Service

Stereochemistry Gordon Research Seminar

2024

Chair

Managed finances, applications, and speaker program

Letters to a Pre-Scientist

2021–2022

STEM Professional

Exchanged letters with rural middle-schoolers about experiences in STEM

Yale Scientific Magazine

2020

Editor in Chief

• Headed editorial and business operations for a national popular science publication

• Performed science demonstrations for local middle- and high-schoolers

• Previously Science Writer and Features Editor